模板效应被认为是离子印迹聚合物(IIP)技术最重要的特征。然而，在模板效应的理论化和将模板效应应用于实践方面还存在一定的空白。在本研究中，我们提出了一种通过调节交联比例来控制IIPs模板效应的方法。合成了一系列不同交联剂含量的Cr(VI)-IIPs。在对配位选择性和模板效应进行定性分析的基础上，利用Scatchard方程建立了交联剂产生的模板效应的理论方程。在Cr(VI)去除过程中，当功能单体与交联剂的摩尔比为1/5.46时，模板效应的贡献开始超过配位效应，且随着交联剂含量的增加，模板效应进一步增强。在实际废水处理应用中，根据所得方程设计的IIP-1/12和IIP-1/6对两种不同类型的废水均能有效处理。本研究提出的标准化方程和设计概念从理论上说明了交联剂对材料选择性的作用。这为离子印迹技术的模板效应的设计和应用提供了更大的灵活性。
\n交联剂对聚合物模板效应的作用:以阴离子印迹聚合物为例数据集，采用实验方法获得，数据格式为十进制(.xls)，数据量为13组，共720条实验数据。", "ds_source": "
室内实验、公式推理，自主产生。", "ds_process_way": "
采用Scatchard模型系数系统软件模块进行建模。实验采用功能单体/交联剂为1/4、1/6、1/8、1/10、1/12、1/15摩尔比的Cr(VI)-IIP与NIP对0.2、2、6 mmol/L等不同离子溶液进行吸附实验，获得数据。", "ds_quality": "
数据质量良好。", "ds_acq_start_time": "2018-09-01 00:00:00", "ds_acq_end_time": "2018-09-30 00:00:00", "ds_acq_place": "江西省南昌市", "ds_acq_lon_east": 115.45, "ds_acq_lat_south": 28.116666666666667, "ds_acq_lon_west": 116.55, "ds_acq_lat_north": 29.166666666666668, "ds_acq_alt_low": null, "ds_acq_alt_high": null, "ds_share_type": "login-access", "ds_total_size": 828660, "ds_files_count": 2, "ds_format": "excel", "ds_space_res": null, "ds_time_res": "日", "ds_coordinate": "无", "ds_projection": "", "ds_thumbnail": "78341ba2-49e5-48b1-93f0-2497a8116377.png", "ds_thumb_from": 0, "ds_ref_way": "", "paper_ref_way": "", "ds_ref_instruction": "使用申明：“交联剂对阴离子印迹聚合物模板效应研究数据集（2018年9月）”来源于国家重点研发计划《大型煤矿和有色矿矿井高效利用技术与示范》（项目编号：2018YFC0406400）。", "ds_from_station": null, "organization_id": "4f9aad20-0a6f-4efd-9b8b-70cd10164ea3", "ds_serv_man": "敏玉芳", "ds_serv_phone": "0931-4967596", "ds_serv_mail": "ncdc@lzb.ac.cn", "doi_value": "10.12072/ncdc.UTCMW.db2131.2022", "subject_codes": [ "170.50" ], "quality_level": 3, "publish_time": "2022-05-30 17:40:05", "last_updated": "2025-06-30 16:28:37", "protected": false, "protected_to": null, "lang": "zh", "cstr": "11738.11.ncdc.UTCMW.db2131.2022", "i18n": { "en": { "title": "Dataset on the Template Effect of Crosslinking Agents on Anionic Imprinted Polymers (September 2018)", "ds_format": "Excel", "ds_source": "
Indoor experiments, formula reasoning, independently generated.", "ds_quality": "
The data quality is good.", "ds_ref_way": "", "ds_abstract": "
The template effect is considered the most important feature of ion imprinted polymer (IIP) technology. However, there is still a certain gap in the theoretical and practical application of template effects. In this study, we propose a method to control the template effect of IIPs by adjusting the crosslinking ratio. A series of Cr (VI) - IIPs with different crosslinking agent contents were synthesized. On the basis of qualitative analysis of coordination selectivity and template effect, a theoretical equation for the template effect generated by crosslinking agents was established using the Scatchard equation. In the Cr (VI) removal process, when the molar ratio of functional monomer to crosslinking agent is 1/5.46, the contribution of template effect begins to exceed that of coordination effect, and with the increase of crosslinking agent content, the template effect is further enhanced. In practical wastewater treatment applications, IIP-1/12 and IIP-1/6 designed based on the obtained equation can effectively treat two different types of wastewater. The standardized equation and design concept proposed in this study theoretically demonstrate the effect of crosslinking agents on material selectivity. This provides greater flexibility for the design and application of template effects in ion imprinting technology.
\nThe effect of crosslinking agents on the template effect of polymers: Taking anionic imprinted polymers as an example dataset, experimental methods were used to obtain data in decimal (. xls) format, with a data volume of 13 groups and a total of 720 experimental data.
", "ds_time_res": "日", "ds_acq_place": "Nanchang City, Jiangxi Province", "ds_space_res": "", "ds_projection": "", "ds_process_way": "Use the Scatchard model coefficient system software module for modeling. The experiment used Cr (VI) - IIP and NIP with functional monomers/crosslinkers in molar ratios of 1/4, 1/6, 1/8, 1/10, 1/12, and 1/15 to perform adsorption experiments on different ion solutions such as 0.2, 2, and 6 mmol/L, and obtained data.", "ds_ref_instruction": "\r\nUsage statement: \"Research dataset on the template effect of crosslinking agents on anionic imprinted polymers (September 2018)\" is sourced from the National Key Research and Development Program \"Efficient Utilization Technology and Demonstration of Large Coal Mines and Nonferrous Mines\" (Project No. 2018YFC0406400)." } }, "submit_center_id": "ncdc", "data_level": 0, "license_type": "https://creativecommons.org/licenses/by/4.0/", "doi_reg_from": "reg_local", "cstr_reg_from": "reg_local", "doi_not_reg_reason": null, "cstr_not_reg_reason": null, "is_paper_in_submitting": false, "ds_topic_tags": [ "交联剂", "模板效应", "离子印迹聚合物" ], "ds_subject_tags": [ "地质学" ], "ds_class_tags": [], "ds_locus_tags": [ "江西省南昌市" ], "ds_time_tags": [ 2018 ], "ds_contributors": [ { "true_name": "杨利明", "email": "yangliming0809185@126.com", "work_for": "南昌航空大学", "country": "中国" } ], "ds_meta_authors": [ { "true_name": "杨利明", "email": "yangliming0809185@126.com", "work_for": "南昌航空大学", "country": "中国" } ], "ds_managers": [ { "true_name": "敏玉芳", "email": "myf@lzb.ac.cn", "work_for": "中国科学院西北生态环境资源研究院", "country": "中国" } ], "category": "其他" }