给出了8类20种高纯手性稀土有机配合物的生产工艺研发过程报告。包括：
\n1 手性吡啶双咪唑啉类稀土配合物（5种）的小试和10克级合成
\n2 手性吡啶双噁唑啉类稀土配合物（4种）的小试和10克级合成
\n3 手性环己二胺Salen稀土配合物（2种）的小试和10克级合成
\n4 手性联萘二氧基磷酸稀土配合物（2种）的小试和10克级合成
\n5 手性苯基噁唑啉稀土配合物（2种）的小试和10克级合成
\n6 手性邻菲啰啉噁唑啉稀土配合物（1种）的小试和10克级合成
\n7 手性席夫碱类稀土配合物（2种）的小试和10克级合成
\n8 手性酚骨架的双脯氨酸酯稀土配合物（2种）的小试和10克级合成
\n满足科研领域对高端手性稀土试剂的制备需要，支撑稀土战略资源在科研试剂领域的高值化、多功能化应用。
", "ds_source": "本资源来源于手性稀土有机配合物的十克级合成研究过程，相关数据采集自北京化工大学合成实验室。通过高精度天平（精确到0.001克）采集反应物的投料量和产物的产量，并计算出产率。通过严格规范合成实验过程，并通过多人、多次验证，保障数据采集的可靠性。产物的结构和纯度通过核磁共振谱、元素分析、手性HPLC测试等方法验证。
", "ds_process_way": "本资源加工方法基于多次有机合成过程和结果。通过详细描述有机合成过程操作，详细记录有机合成过程的数据，并通过多次验证实验，整理出高纯手性稀土有机配合物的生产工艺文件。
", "ds_quality": "本资源来源于手性稀土有机配合物的十克级合成研究过程，相关数据采集自北京化工大学合成实验室。通过高精度天平（精确到0.001克）采集反应物的投料量和产物的产量，并计算出产率。通过严格规范合成实验过程，并通过多人、多次验证，保障数据采集的可靠性。
", "ds_acq_start_time": "2022-11-01 00:00:00", "ds_acq_end_time": "2025-12-31 00:00:00", "ds_acq_place": "", "ds_acq_lon_east": null, "ds_acq_lat_south": null, "ds_acq_lon_west": null, "ds_acq_lat_north": null, "ds_acq_alt_low": null, "ds_acq_alt_high": null, "ds_share_type": "apply-access", "ds_total_size": 678916, "ds_files_count": 0, "ds_format": "*.docx", "ds_space_res": "", "ds_time_res": "", "ds_coordinate": "无", "ds_projection": "", "ds_thumbnail": "a7db8454-506c-4566-abe0-79d48c5be707.png", "ds_thumb_from": 2, "ds_ref_way": "", "paper_ref_way": "", "ds_ref_instruction": "", "ds_from_station": "", "organization_id": "af683ce0-400b-4f2f-9242-f45f0621e11a", "ds_serv_man": "李红星", "ds_serv_phone": "0931-4967592", "ds_serv_mail": "ncdc@lzb.ac.cn", "doi_value": "", "subject_codes": [ "410" ], "quality_level": 0, "publish_time": "2026-05-21 11:05:45", "last_updated": "2026-05-21 11:08:26", "protected": false, "protected_to": null, "lang": "zh", "cstr": "", "i18n": { "en": { "title": "A dataset of research and development process for the production process of 20 high-purity chiral rare earth organic complex reagents in 8 categories", "ds_format": "*.docx", "ds_source": "This resource comes from the ten gram level synthesis research process of chiral rare earth organic complexes, and the relevant data was collected from the Synthesis Laboratory of Beijing University of Chemical Technology. Collect the feeding amount of reactants and the yield of products using a high-precision balance (accurate to 0.001 grams), and calculate the production rate. By strictly regulating the synthesis experiment process and verifying it multiple times with multiple people, the reliability of data collection is ensured. The structure and purity of the product were verified by methods such as nuclear magnetic resonance spectroscopy, elemental analysis, and chiral HPLC testing.
", "ds_quality": "This resource comes from the ten gram level synthesis research process of chiral rare earth organic complexes, and the relevant data was collected from the Synthesis Laboratory of Beijing University of Chemical Technology. Collect the feeding amount of reactants and the yield of products using a high-precision balance (accurate to 0.001 grams), and calculate the production rate. By strictly regulating the synthesis experiment process and verifying it multiple times with multiple people, the reliability of data collection is ensured.
", "ds_ref_way": "", "ds_abstract": "A report on the production process research and development of 8 types and 20 high-purity chiral rare earth organic complexes was provided. Including:
\r\nSmall scale experiments and 10 gram scale synthesis of chiral pyridine bis imidazoline rare earth complexes (5 types)
\r\nSmall scale experiments and 10 gram scale synthesis of chiral pyridine bisoxazoline rare earth complexes (4 types)
\r\nSmall scale experiments and 10 gram scale synthesis of 3 chiral cyclohexanediamine Salen rare earth complexes (2 types)
\r\nSmall scale experiments and 10 gram level synthesis of 4-chiral naphthalene dioxy phosphate rare earth complexes (2 types)
\r\nSmall scale experiments and 10 gram level synthesis of 5 chiral phenyl oxazoline rare earth complexes (2 types)
\r\nSmall scale experiment and 10 gram level synthesis of rare earth complexes with 6-chiral ortho phenanthroline and oxazoline (1 type)
\r\nSmall scale experiments and 10 gram level synthesis of 7 chiral Schiff base rare earth complexes (2 types)
\r\nSmall scale experiments and 10 gram level synthesis of rare earth complexes with dual proline esters based on 8-chiral phenolic frameworks (2 types)
\r\nMeet the preparation needs of high-end chiral rare earth reagents in the scientific research field, and support the high-value and multifunctional application of rare earth strategic resources in the field of scientific research reagents.
", "ds_time_res": "", "ds_acq_place": "", "ds_space_res": "", "ds_projection": "", "ds_process_way": "This resource processing method is based on multiple organic synthesis processes and results. By providing a detailed description of the organic synthesis process operation, recording the data of the organic synthesis process in detail, and conducting multiple verification experiments, a production process document for high-purity chiral rare earth organic complexes has been compiled.
", "ds_ref_instruction": "" } }, "submit_center_id": "ncdc", "data_level": 0, "recommendation_value": 0, "license_type": "https://creativecommons.org/licenses/by/4.0/", "doi_reg_from": "reg_local", "cstr_reg_from": "reg_local", "doi_not_reg_reason": null, "cstr_not_reg_reason": null, "is_paper_in_submitting": false, "ds_topic_tags": [ "高纯手性稀土有机配合物", "生产工艺文件研发", "过程报告" ], "ds_subject_tags": [ "工程与技术科学基础学科" ], "ds_class_tags": [], "ds_locus_tags": [], "ds_time_tags": [], "ds_contributors": [ { "true_name": "许家喜", "email": "jxxu@buct.edu.cn", "work_for": "北京化工大学", "country": "中国" }, { "true_name": "杨占会", "email": "zhyang@buct.edu.cn", "work_for": "北京化工大学", "country": "中国" } ], "ds_meta_authors": [ { "true_name": "杨占会", "email": "zhyang@buct.edu.cn", "work_for": "北京化工大学", "country": "中国" } ], "ds_managers": [ { "true_name": "杨占会", "email": "zhyang@buct.edu.cn", "work_for": "北京化工大学", "country": "中国" } ], "category": "其他" }